| YEAR | DATE | EVENT | GOVERNOR |
| 1541 | 12 february | Nueva Extremadura Part of Peru | |
| 1692 | 5 january | Tomás Marín de Poveda | |
| 1700 | 17 december | Francisco Ibáñez de Peralta | |
| 1709 | 27 january | Juan Andrés de Ustáriz | |
| 1716 | 23 december | José Santiago Concha | |
| 1717 | 16 december | Gabriel Cano y Aponte | |
| 1733 | Francisco Sánchez de la Barreda y Vera | ||
| 1733 | 29 january | Manuel de Salamanca | |
| 1737 | 15 november | José Antonio Manso de Velasco, duque de Superunda | |
| 1745 | 4 june | Francisco José de Obando | |
| 1746 | 25 march | Domingo Ortíz de Rosas | |
| 1755 | 28 march | Manuel de Amat y Junient | |
| 1761 | 9 september | Félix de Berroeta | |
| 1762 | 3 october | Antonio de Guill y Gonzaga | |
| 1768 | 17 january | Juan de Balmaceda y Censano y Beltrán | |
| 1770 | 3 march | Francisco Javier de Morales y Castejón y Arroyo | |
| 1773 | 6 march | Augustín de Jáuregui y Aldecoa | |
| 1780 | 6 july | Tomás Álvarez de Acevedo (I) | |
| 1780 | 10 december | Ambrosio de Benavides Medina Liñán y Torre | |
| 1787 | 10 july | Tomás Álvarez de Acevedo (II) | |
| 1788 | april | Ambrosio O'Higgins y Ballenary, marqués de Osorno | |
| 1796 | 16 may | José de Rezabal y Ugarte | |
| 1796 | 18 september | Gabriel de Avilés y del Fierro, marqués de Avilés | |
| 1799 | 21 january | Joaquín del Pino y Rosas | |
| 1801 | 6 april | José de Santiago Concha | |
| 1801 | 31 december | Francisco Tadeo de Medina | |
| 1802 | 30 january | Luis Antonio Muñoz de Guzmán | |
| 1808 | february | Juan Rodríguez Ballesteros | |
| 1808 | 22 april | Francisco Antonio García Carrasco Díaz (I) | |
| 1810 | 16 july | Mateo de Toro y Zambrano y Ureta conde de la Conquista |